Selectivity and Mechanism of Hydrogen Atom Transfer by an Isolable Imidoiron(III) Complex
نویسندگان
چکیده
منابع مشابه
Selectivity and mechanism of hydrogen atom transfer by an isolable imidoiron(III) complex.
In the literature, iron-oxo complexes have been isolated and their hydrogen atom transfer (HAT) reactions have been studied in detail. Iron-imido complexes have been isolated more recently, and the community needs experimental evaluations of the mechanism of HAT from late-metal imido species. We report a mechanistic study of HAT by an isolable iron(III) imido complex, L(Me)FeNAd (L(Me) = bulky ...
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Al13H-: hydrogen atom site selectivity and the shell model.
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A mononuclear high-valent trans-dioxoruthenium(VI) complex, trans-[Ru(VI)(TMC)(O)2](2+) (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane), was synthesized and characterized by various spectroscopic techniques and X-ray crystallography. The reactivity of the trans-[Ru(VI)(TMC)(O)2](2+) complex was investigated in hydride transfer and hydrogen atom transfer reactions. The mechanism o...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2011
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja2005303